トップページへ戻る
 
ご購入案内 小会案内 ENGLISH b
書籍詳細




Organoboranes in Organic Syntheses
鈴木 章著

判型: B5変型 上製
頁数: 242
ISBN: 978-4-8329-0362-3
Cコード: C3043
発行日:2010-12-15
定価: 3,024円 (本体価格2,800円+税)

在庫あり
カートに入れる:
●本書の特徴

2010年度ノーベル化学賞を受賞した鈴木カップリングについての基本論文集。有機ホウ素化合物のクロスカップリング反応に関する重要論文を収録。触媒科学や材料化学の分野で多大な影響を与えたことの顕著な業績集であり,化学関係者とくに研究者の卵にとっては必読の論文集。
●目次

Foreword………Herbert C. Brown
Acknowledgment

1 About the Author
   Research on Organoborane Chemistry / Sketch of Professor Akira Suzuki's Life / 
   Awards / List of Publications (1967-2003)

2 Organoboranes as Sources of Organic Radicals
   Introduction / Reactions with α,β-Unsaturated Carbonyl Compounds / Oxygen-
   Induced Reaction of Trialkylboranes with Alkyl Halides. A Facile Coupling of Allylic and 
   Benzylic Halides via Triethylborane / A New Four-Carbon-Atom Homologation Involving 
   the Free-Radical Chain Reaction of 1,3-Butadiene Monoxide with Organoboranes / Two 
   Novel Reactions of Monomeric Formaldehyde with Trialkylboranes. A Remarkable Rapid 
   Elimination Diverted by Oxygen to a Free-Radical Chain Addition / A Convenient 
   Synthesis of α-Bromoketones from Vinyloxyboranes Obtained by the Reaction of 
   Organoboranes with α,β-Unsaturated Ketones in the Presence of a Catalytic Amount 
   of Oxygen / Oxygen-Induced 1,4-Addition Reaction of Organoboranes to 
   Crotonaldimine / Reaction of Organoboranes with 1-Acyl-2-vinylcyclopropanes in the 
   Presence of Oxygen / Reaction of Organoboranes with d-Carvone and l-Perillaldehyde 
   in the Presence of Oxygen. Evidence for Coordination between Organoboranes and α,
   β-Unsaturated Carbonyl Oxygen in their Oxygen-Induced Free-Radical Reaction 
   Process / Reaction of Organoboranes with Iron(III) Azide in the Presence of Hydrogen 
   Peroxide. A Novel Synthesis of Azidoalkanes

3 Organic Syntheses Using Organoborates
   Introduction / Preparation of Tetracoordinate Organoborates / Synthesis via 
   Organoborates (R3B-X-Y) with Latent Leaving Groups (Y) in the α-Position / Synthesis 
   via Alkynylborates and Alkenylborates / Synthesis via Copper(I) Tetraorganoborates 
   and Related Compounds / Miscellaneous Reactions / Summary

4 Haloboration of 1-Alkynes and Its Synthetic Application
   Introduction / Organic Synthesis via Haloboration Adducts Prepared from B-Halo-9-
   BBN / Organic Synthesis via Haloboration Adducts Prepared from Tribromoborane / 
   Conclusion

5 Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds with Organic 
  Electrophiles
   Introduction / Synthesis of Organoboron Reagents / Palladium-Catalyzed Reactions of 
   Organoboron Compounds and Their Mechanism / Cross-Coupling Reaction / Head-to-
   Tail Coupling / Carbonylative Coupling / Alkoxycarbonylation and Dimerization / 
   Conclusion


●著者紹介

Akira Suzuki(Akira Suzuki)
1930年 北海道鵜川町に生まれる
1960年 北海道大学大学院理学研究科博士課程修了 
現 在  北海道大学名誉教授 理学博士
      2010年度ノーベル化学賞受賞



北海道大学出版会
〒060-0809 北海道札幌市北区北9条西8丁目北海道大学構内
TEL 011-747-2308(直通) FAX 011-736-8605
Copyrights(C) HOKKAIDO UNIVERSITY PRESS ALL RIGHTS RESERVED