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Organoboranes in Organic Syntheses
鈴木 章著

判型: B5変型 上製
頁数: 242
ISBN: 978-4-8329-0362-3
Cコード: C3043
発行日:2010-12-15
定価: 3,024円 (本体価格2,800円+税)

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●本書の特徴

2010年度ノーベル化学賞を受賞した鈴木カップリングについての基本論文集。有機ホウ素化合物のクロスカップリング反応に関する重要論文を収録。触媒科学や材料化学の分野で多大な影響を与えたことの顕著な業績集であり,化学関係者とくに研究者の卵にとっては必読の論文集。
●目次

Foreword  Herbert C. Brown

Acknowledgment

1 About the Author
  Research on Organoborane Chemistry / Sketch of Professor Akira Suzuki's Life / Awards / List of
 Publications (1967-2003)

2 Organoboranes as Sources of Organic Radicals
  Introduction / Reactions with α,β-Unsaturated Carbonyl Compounds / Oxygen-Induced Reaction
 of Trialkylboranes with Alkyl Halides. A Facile Coupling of Allylic and Benzylic Halides via  
 Triethylborane / A New Four-Carbon-Atom Homologation Involving the Free-Radical Chain Reaction
 of 1,3-Butadiene Monoxide with Organoboranes / Two Novel Reactions of Monomeric Formaldehyde
 with Trialkylboranes. A Remarkable Rapid Elimination Diverted by Oxygen to a Free-Radical Chain
 Addition / A Convenient Synthesis of α-Bromoketones from Vinyloxyboranes Obtained by the
 Reaction of Organoboranes with α,β-Unsaturated Ketones in the Presence of a Catalytic Amount
 of Oxygen / Oxygen-Induced 1,4-Addition Reaction of Organoboranes to Crotonaldimine / Reaction
 of Organoboranes with 1-Acyl-2-vinylcyclopropanes in the Presence of Oxygen / Reaction of
 Organoboranes with d-Carvone and l-Perillaldehyde in the Presence of Oxygen. Evidence for
 Coordination between Organoboranes and α,β-Unsaturated Carbonyl Oxygen in their
 Oxygen-Induced Free-Radical Reaction Process / Reaction of Organoboranes with Iron(III) Azide in
 the Presence of Hydrogen Peroxide. A Novel Synthesis of Azidoalkanes

3 Organic Syntheses Using Organoborates
  Introduction / Preparation of Tetracoordinate Organoborates / Synthesis via Organoborates
 (R3B-X-Y) with Latent Leaving Groups (Y) in the α-Position / Synthesis via Alkynylborates and
 Alkenylborates / Synthesis via Copper(I) Tetraorganoborates and Related Compounds /
 Miscellaneous Reactions / Summary

4 Haloboration of 1-Alkynes and Its Synthetic Application
  Introduction / Organic Synthesis via Haloboration Adducts Prepared from B-Halo-9-BBN / Organic
 Synthesis via Haloboration Adducts Prepared from Tribromoborane / Conclusion

5 Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds with Organic Electrophiles
  Introduction / Synthesis of Organoboron Reagents / Palladium-Catalyzed Reactions of
 Organoboron Compounds and Their Mechanism / Cross-Coupling Reaction / Head-to-Tail Coupling
 / Carbonylative Coupling / Alkoxycarbonylation and Dimerization / Conclusion
●著者紹介

Akira Suzuki(Akira Suzuki)
1930年 北海道鵜川町に生まれる
1960年 北海道大学大学院理学研究科博士課程修了 
現 在  北海道大学名誉教授 理学博士
      2010年度ノーベル化学賞受賞



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